Thermodynamic Excess Properties and Intermolecular Interaction Using Fourier Transform Infrared for the Dodecylbenzenesulfonic Acid-Acetone Binary Liquid Mixture

Ali A. Jazie

doi:10.14500/aro.10229

Ali A. Jazie Department of Chemical Engineering, University of Al-Qadisiyah, Al-Qadisiyah, Al-Diwaniyah http://orcid.org/0000-0002-0409-7001

Keywords: Acetone, Density, Dodecylbenzenesulfonic acid, Excess properties, Fourier Transform infrared spectral analysis, Hydrogen bonding, Intermolecular interaction, Surface tension, Viscosity

Abstract

Density, viscosity, and surface tension for the DBSA-Acetone system at the temperatures (293.15, 298.15, 301.15 K) have been investigated experimentally. Excess molar volume, viscosity deviation, surface tension deviation, and molar excess Gibbs free energy deviation are calculated at (293.15, 298.15, 301.15 K). All the non-ideal properties calculated are fitted to Redlich-Kister (RK) equation. FTIR spectrum of the DBSA-Acetone mixture have been characterized for studying the intermolecular interaction. The result of molar excess Gibbs free energy deviation and FTIR studies showed a weak hydrogen bonding for the mixture solution. While, the intramolecular interaction is strong in the case of pure DBSA and acetone due to the self-association of DBSA molecule or decreasing the dipole-dipole of acetone molecule. The result of FTIR supported the result of thermodynamic excess where the excess molar volumes were positive. The calculated values of excess molar volume are positive for all the temperatures ranging from (293.15 - 301.15 K). while, the values of viscosity deviation, surface tension deviation, and molar excess Gibbs free energy deviation are negative for all the temperatures studied.

Downloads

Download data is not yet available.

Author Biography

Ali A. Jazie, Department of Chemical Engineering, University of Al-Qadisiyah, Al-Qadisiyah, Al-Diwaniyah

Ali A. Jazie received his Ph.D. degree in Chemical Engineering and Technology from IIT/BHU in 2013. His main research interest is chemical reaction engineering and catalysis. Also, he is interested in the field of Biofuel, Recycling, Renewable energy and Thermodynamic. He is a staff member of the Chemical Engineering Department, College of Engineering, Alqadisyiah University, Iraq. He was the Head of the Chemical Engineering Department during the years 2014-2015. He published more than 15 papers in international and national journals, and attended many international and national conferences. Dr. Jazie is a member of the Institute of Research Engineers and Doctors (IRED), Asia-Pacific Chemical, Biological & Environmental Engineering Society (APCBEES) and the Iraqi Engineers Union.

References

Ancian, B., Tiffon, B. and Dubois, J.E., 1983. Molecular interactions and reorientational motion of neat acetone in the liquid state. 17 O NMR chemical shifts and linewidths at variable temperature. Chemical Physics, 74(2), pp.171-177.

Arivazhagan, G., Elangovan, A., Shanmugam, R., Vijayalakshmi, R. and Kannan, P.P., 2015. Spectroscopic studies, NBO analysis and dielectric studies on the behaviour of acetone molecules in non-polar solvent environment. Chemical Physics Letters, 627, pp.101-106.

Bajić, D.M., Ivaniš, G.R., Visak, Z.P., Živković, E.M., Šerbanović, S.P. and Kijevčanin, M.L., 2013a. Densities, viscosities, and refractive indices of the binary systems (PEG200+1, 2-propanediol,+1, 3-propanediol) and (PEG400+1, 2-propanediol,+1, 3-propanediol) at (288.15 to 333.15) K and atmospheric pressure: Measurements and modeling. The Journal of Chemical Thermodynamics, 57, pp.510-529.

Bajić, D.M., Jovanović, J., Živković, E.M., Visak, Z.P., Šerbanović, S.P. and Kijevčanin, M.L., 2013b. Experimental measurement and modelling of viscosity of the binary systems pyridine or nicotine with polyethylene glycols at T=(288.15–333.15) K. New UNIFAC–VISCO and ASOG–VISCO interaction parameters. Fluid Phase Equilibria, 338, pp.282-293.

Chai, Y., Dong, D., Ouyang, Y., Liang, Y., Wang,Y., Li, M. and Liu, Q., 2007. Thia-michael addition reactions in water using 3-[Bis(Alkylthio) methylene] pentane-2,4-diones as odorless and efficient thiol equivalents. Letters Organic Chemistry, 4, pp.281.

Dash, U.N. and Mohanty, B.K., 1997. Thermodynamic functions of solutions of homologous dicarboxylic acids in water+acetone mixtures from surface tension measurements. Fluid Phase Equilibria, 134(1-2), pp.267-276.

Gnanakumari, P., Venkatesu, P., Mohan, K.R., Rao, M.P. and Prasad, D.H.L., 2007. Excess volumes and excess enthalpies of N-methyl-2-pyrrolidone with branched alcohols. Fluid Phase Equilibria, 252(1), pp.137-142.

Haba, Y., Segal, E., Narkis, M., Titelman, G.I. and Siegmann, A., 1999. Polymerization of aniline in the presence of DBSA in an aqueous dispersion. Synthetic Metals, 106(1), pp.59-66.

Han, M.G., Cho, S.K., Oh, S.G. and Im, S.S., 2002. Preparation and characterization of polyaniline nanoparticles synthesized from DBSA micellar solution. Synthetic Metals, 126(1), pp.53-60.

Hasan, M., Hiray, A.P., Kadam, U.B., Shirude, D.F., Kurhe, K.J. and Sawant, A.B., 2011. Densities, viscosities, speeds of sound, FT-IR and 1H-NMR studies of binary mixtures of n-butyl acetate with ethanol, propan-1-ol, butan-1-ol and pentan-1-ol at 298.15, 303.15, 308.15 and 313.15 K. Journal of Solution Chemistry, 40(3), pp.415-429.

Jalilian, M.R. and Zahedi-Tabrizi, M., 2008. Spectra and structure of binary azeotropes V-acetone–cyclopentane. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 69(1), pp.278-281.

Jing, L., Li, X., Che Li, X., ChunHan, Y. and Chu, Y., 2008. The esterification in cyclohexane/DBSA/water microemulsion system. Colloid Surface A: Physicochemical Engineering, 326, pp.37.

Knözinger, E. and Wittenbeck, R., 1984. Far-infrared spectra of strongly polar molecules in solid solution: Acetone and nitromethane. Journal of Molecular Spectroscopy, 105(2), pp.314-323.

Kollipost, F., Domanskaya, A.V. and Suhm, M.A., 2014. Microscopic roots of alcohol-ketone demixing: Infrared spectroscopy of methanol-acetone clusters. The Journal of Physical Chemistry A, 119(11), pp.2225-2232.

Kumar, V., Yokozeki, T., Goto, T. and Takahashi, T., 2016. Synthesis and characterization of PANI-DBSA/DVB composite using roll-milled PANI-DBSA complex. Polymer, 86, pp.129-137.

Liu, Y., Jia, L., Guo, X. and Zhao, Z., 2017. Surface activities and thermodynamic properties of novel cationic surfactants with hydroxymethyl group. Journal of Dispersion Science and Technology, 38(2), pp.236-240.

Machado, D.S., Moraes, S.R. and Motheo, A.J., 2006. Aspects of the chemical synthesis of PAni-DBSA and its properties. Molecular Crystals and Liquid Crystals, 447(1), pp.215-533.

Manabe, K., Lumura, S., Sun, X. and Kobayashi, S., 2002. Dehydration reactions in water. Brønsted acid-surfactant-combined catalyst for ester, ether, thioether, and dithioacetal formation in water. Jurnal American Chemical Society, 124, pp.11971.

Manabe, K., Mori, Y. and Kobayashi, S., 2001. Three-component carbon-carbon bond-forming reactions catalyzed by a Brønsted acid-surfactant-combined catalyst in water. Tetrahedron, 57(13), pp.2537-2544.

Qian, L.I.U., Zhang, S., Shaochuan, S.H.E., Junxian, Y.U.N. and Kejian, Y.A.O., 2011. Density and viscosity of ternary systems (poloxamer 188+ethanol/ acetone+water) at temperatures from 288.15 K to 308.15 K. Chinese Journal of Chemical Engineering, 19(3), pp.478-483.

Schindler, W., Sharko, P.T. and Jonas, J., 1982. Raman study of pressure effects on frequencies and isotropic line shapes in liquid acetone. The Journal of Chemical Physics, 76(7), pp.3493-3496.

Shikata, T., Sugimoto, N., Sakai, Y. and Watanabe, J., 2012. Dielectric behaviors of typical benzene monosubstitutes, bromobenzene and benzonitrile. The Journal of Physical Chemistry B, 116(41), pp.12605-12613.

Shiri, M. and Zolfigol, M.A., 2009. Surfactant-type catalysts in organic reactions. Tetrahedron, 65(3), pp.587-598.

Shrikhande, J.J. 2007. p-Dodecylbenzenesulfonic acid: A Brønsted acid-surfactant-combined catalyst. Research Jurnal Chemical Environmental, 11, pp.82.

Srivastava, S.K., Ojha, A.K., Koster, J., Shukla, M.K., Leszczynski, J., Asthana, B.P. and Kiefer, W., 2003. Isotopic dilution, self-association, and Raman non-coincidence in the binary system (CH3)2C=O+(CD3)2C=O reinvestigated by polarized Raman measurement and ab initio calculations. Journal of Molecular Structure, 661, pp.11-21.

Tahery, R., 2017. Surface tension and density of mixtures of m-xylene+n-alkane at 293.15 K: Analysis under the extended langmuir and shereshefsky models. The Journal of Chemical Thermodynamics, 106, pp.95-103.

Wei, Q., Guo, X., Wang, Y. and Yang, H., 2013. Temperature-dependent FTIR study on three kinds of hydrogen-bonded benzoic acid dimers in their melt states. Journal of Molecular Liquids, 177, pp.225-228.