Synthesis and Characterization of Iron(II), Cobalt(II), Nickel(II), Copper(II), and Zinc(II) Complexes Using Diphenylmethyl Xanthate Ligand

Keywords: Four-coordinate complexes, Potassium diphenylmethyl xanthate ligand, Structural study, Xanthate complexes

Abstract

Potassium Diphenylmethyl Xanthate and its monomeric complexes were synthesized at room temperature under inert gas and stirring condition. The ligand and its complexes of the general formula [M(L)2] (where M= FeII, CoII, NiII , CuII, ZnII and CdII) were characterized by spectroscopic methods (IR, UV-Vis, 1H-, 13C-, DEPT-, HQMC- and COSY-NMR), elemental analysis, metal content, magnetic susceptibility  measurement and molar conductance. These studies revealed the formation of four coordinate complexes.

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Author Biographies

Aeed S. Al-Fahdawi, Department of Chemistry, College of Education for Women, University of Anbar, Ramadi, Anbar
Dr. Aeed Salih Mohammed is an Assistant Professor. He joined the Department of Chemistry, College of Education for Women at the the University of Anbar in 2001. He  has a B.Sc. degree in Chemistry, M.Sc. degree in Inorganic Chemistry and Ph.D. degree in Inorganic Chemistry, he has (10) published Journal Articles.
Eman I. Alsalihi, Department of Chemistry, Faculty of Science and Health, Koya university, Kurdistan Region

Dr. Eman Ibraheem Alsalihi is a Lecturer, joined the Department of Chemistry, Faculty of Science and HEalth at Koya University in 2009. She has a B.Sc. degree in Chemistry, M.Sc. degree in Inorganic Chemistry and Ph.D. degree in Inorganic Chemistry. She is a membership of the ACS (American Chemical Society) since 2015 . Dr. Eman has (10) published Journal articles. 

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Published
2018-05-25
How to Cite
Al-Fahdawi, A. S. and Alsalihi, E. I. (2018) “Synthesis and Characterization of Iron(II), Cobalt(II), Nickel(II), Copper(II), and Zinc(II) Complexes Using Diphenylmethyl Xanthate Ligand”, ARO-THE SCIENTIFIC JOURNAL OF KOYA UNIVERSITY, 6(1), pp. 33-37. doi: 10.14500/aro.10243.
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Articles