Synthesis and Characterization of Sodium Diphenylcarbamodithioate Ligand [L] and its Cobalt, Nickel, and Copper Complexes

  • Eman I. Alsalihi Department of Chemistry, Faculty of Science and Health, Koya University, Kurdistan Region http://orcid.org/0000-0003-3271-8490
  • Aeed S. Al-Fahdawi Department of Chemistry, College of Education for Women, University of Anbar, Ramadi, Anbar
  • Bashdar I. Meena Department of Chemistry, Faculty of Science and Health, Koya University, Kurdistan Region
DOI: https://doi.org/10.14500/aro.10198
Keywords: Diphenylcarbamodithioate complexes, Four-coordinate square planar complexes, Sodium diphenylcarbamodithioate ligand, Structural study

Abstract

A correlation of the infrared spectra of thiocarbonyl derivatives based on the literature data has been carried out. Assignments have also been made in some new systems. Sodium Diphenylcarbamodithioate ligand and its monomeric complexes were synthesized at room temperature and stirring condition. The ligand and its complexes of the general formula [M(L)2] (where M= Co+2, Ni+2  and Cu+2) were characterized by spectroscopic methods (IR and ultraviolet-visible), elemental analysis (C.H.N. and S) metal content, magnetic susceptibility measurement, and biological activity (an antibacterial activity of the complex was studied by agar disc diffusion method and minimum inhibitory concentration strain against Staphylococcus aureus and Bacillus subtilis). The complex exhibited significant activities against S. aureus and B. subtilis, thin-layer chromatography, mass spectrometry, X-ray powder diffraction, and molar conductance. Our study revealed the formation of four-coordinate square planar complexes around Coп, Niп, and Cuп metal ions.

Downloads

Download data is not yet available.

Author Biography

Eman I. Alsalihi, Department of Chemistry, Faculty of Science and Health, Koya University, Kurdistan Region

Dr. Eman Ibraheem Alsalihi is a lecturer, joined the department of chemistry, Faculty of Science and Health at Koya University in 2009. She has a B.Sc. degree in chemistry, M.Sc. degree in inorganic chemistry and Ph.D. degree in inorganic chemistry. She is a member of the ACS (American chemical society) since 2015. Dr. Eman has (10) published Journal Articles.

References

Al-Fahdawi, A.S., Al-Kafajy, H.A., Al-Jeboori, M.J. and Potgieter, H., 2014. New bimetallic bisdithiocarbameta-based macrocyclic complex; Preparation and spectral characterization. Chem-Xpress, 4(3), pp.262-267.

Al-Fahdawi, A.S. and Al-Salihi, I.I., 2015. Preparation of Tris (diphenyl methanol) binding by hydrogen bonds through the application of microwave techniques. International Journal of Current Research in Biosciences and Plant Biology, 2(7), pp.1-9.

Al-Jeboori, M.J., Al-Tawel, H.H. and Mahmood, R., 2010. New metal complexes of N2S2 tetradentate ligands: Synthesis and spectral studies. Inorganica Chimica Acta, 363(6), pp.1301-1305.

Amy, L., Pochodylo, R.L., LaDuca, 2011. A layered grid divalent cobalt coordination polymer constructed from ferromagnetically coupled linear trimeric units. Inorganic Chemistry Communications, 14, pp.722-726

Anacona, J.R. and Patiño, C., 2006. Metalloantibiotics: Synthesis and antibacterial activity of ceftazidime metal complexes. Journal of Coordination Chemistry, 54, pp.355-365.

Anuradha, K. and Rajarel, R., 2011. Synthesis, spectral characterization and biological activity of new symmetrical macrocyclic binuclear Schiff base complexes. International Journal of Pharmacy and Technology, 3(2), pp.2217.

Bailey, J.H.E., Drake, J.E., and Wong, M.L.Y., 1991. WONG Department of Chemistry and Biochemistry, University of Windsor, Windsor, Ont., Canada N9B 3P4. Preparation and characterization of a series of bromodiphenyl(N,N-dialkyldithiocarbamato)tellurium(IV) compounds where R = Me, Et, i-Pr, Bu, and of chlorodiphenyl(N,N-dibutyldithiocarbamato)tellurium(IV) and diphenylbis(N, N-dibutyldithiocarbamato)tellurium(IV). Crystal structure of Ph2TeBr[S2CNEt2] and Ph2Te[S2CNBu2I2, http://www.nrcresearchpress.com/ doi/pdfplus/10.1139/v91-280. [Last received on 1991 Apr 18].

Beer, P.D., Cowley, A.R., Jeffery, J.C., Paul, R.L. and Wong, W.W.H., 2003. Self-assembled xanthate-transition metal polyether macrocycles and cryptands. Polyhedron, 22(5), pp.795-801.

Bensebaa, F., Zhou, Y., Brolo, A.G., Irish, D. E., Deslandes, Y., Kruus, E. and Ellis, T.H., 1999. Raman characterization of metal-alkanethiolates. Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy, 55(6), pp.1229.

Canady, R., Richard, L., Greg, P., Margaret, W., Heidi, B., Steven, H., Brent, K., Ji-Eun, L., Craig, L. and Joseph, S., 2013. Determining the applicability of threshold of toxicological concern approaches to substances found in foods. Critical Reviews in Food Science and Nutrition, 53 (12), pp.239-1249.

Dokken, K.M., Parsons, J.G., McClure, J. and Gardea-Torresdey, J.L. 2009. Synthesis and structural analysis of copper(II) cysteine complexes. Inorganica Chimica Acta, 362, pp.395-401.

El-Shazly, R.M., Al-Hazmi, G.A., Ghazy, S.E., El-Shahawi, M.S. and El- Asmy, A.A., 2005. Spectroscopic, thermal and electrochemical studies on some nickel (II) thiosemicarbazone complexes. Spectrochimica Acta A, 61, pp.243.

Griffith, D.M., Szocs, B., Keogh, T., Suponitsky, K.Y., Farkas, E., Buglyo, P. and Marmion, C.J., 2011. Suberoylanilide hydroxamic acid, a potent histone deacetylase inhibitor; its X-ray crystal structure and solid state and solution studies of its Zn(II), Ni(II), Cu(II) and Fe(III) complexes. Journal of Inorganic Biochemistry, 105, pp.763-769.

Guillemet-Fritsch, S., Lebey, T., Boulos, M. and Durand, B., 2006, Dielectric properties of CaCu3Ti4O12 based multiphased ceramics. Journal of the European Ceramic Society, 26, pp.1245-1257.

Holleman, A.F. and Wiberg, E., 2001. Inorganic Chemistry. Academic Press, San Diego.

Ingle, M., and D’Souza, M.C., 1989. Physiology and control of superficial scald of apples: A review. Horticultural Science, 24(28), pp.31.

Kai, Y., Gu, Z., Ji, R. and Lou, L.S., 2009. Heterogeneous chiral Mn(111) salen catalysts for the epoxidation of unfunvtionalized olefins immobilized on mesoporous materials with different pore sizes. Tetrahedron, 65, pp.305-311.

Kavitha, N. and Lakshm, P.V.A., 2017. Synthesis, characterization and thermogravimetric analysis of Co(II), Ni(II), Cu(II) and Zn(II) complexes supported by ONNO tetradentdate Schiff base ligand derived from hydrazine benzoxazine. Journal of Saudi Chemical Society, 21 Suppl 1, pp.S457-S466.

Manishankar, P., Sarpudeen, A. and Viswanathan, S., 2001. Electroanalysis of dapsone, an anti-leprotic drug. Journal of Pharmaceutical and Biomedical Analysis, 26, pp. 873-881.

Petra, D., Tatjano, Z. and Boriset, P., 2005. Mixed-valence Cu(II)/Cu(I) complex of quinolone ciprofloxacin isolated by a hydrothermal reaction in the presence of l-histidine: Comparison of biological activities of various copper-ciprofloxacin compounds. Journal of Inorganic Biochemistry, 2, pp.432-442.

Roeges, N.G.P., 1994. A Guide to the Complete Interpretation of the Infrared Spectra of Organic Structures. Wiley, New York.

Saadeh, S.M., 2013. Synthesis, characterization and biological properties of Co(II), Ni(II),Cu(II) and Zn(II) complexes with an SNO functionalized ligand. Arabian Journal of Chemistry, 6, pp.191-196.

Seleem, H.S., El-Inany, G.A., El-Shetary, B.A. and Mousa, M.A., 2011. The ligational behavior of an isatinic quinolyl hydrazone towards copper(II)-ions. Chemistry Central Journal, 5, pp.20.

Semalty, A., Semalty, M. and Rawat, M.S., 2010. Development and characterization of aspirin-phospholipid complex for improved drug delivery. International Journal of Pharmaceutical Science and Nano Technology, 3, pp.940-947.

Sultana, N. and Arayne, M.S., 2007. In vitro activity of cefadroxil, cephalexin, cefatrizine and cefpirome in presence of essential and trace elements. Pakistan Journal of Pharmaceutical Sciences, 20(4), pp.305-310.

Tauber, S.C. and Nau, R., 2008. Immunomodulatory properties of antibiotics. Current Molecular Pharmacology, 1, pp.68.

Uppadin, L.H., Weeks, J.M. and Beer, P.D., 2001. Metal-directed self-assembly of terphenyl based dithiocarbamate ligands. Journal of the Chemical Society Dalton Transactions, 22, pp.3367-3372.

Venkataraghavana, R. and Raoa, C.N.R., 2005. The C=S stretching frequency and the “-N-C=S bands” in the infrared. Spectrochimica Acta A, 18(4), pp.541-547.

Vogt, P.F. and Gerulis, J.J., 2005. Amines, aromatic. In: Ullmann’s Encyclopedia of Industrial Chemistry. Wiley-VCH, Weinheim.

Zheng, Z., Junwei, X., Sisi, Y., Yangli, C., Yan, W., Zhuo, C. and Chunlin, N., 2017. Two organic cation salts containing tetra(isothiocyanate)cobaltate(II): Synthesis, crystal structures, spectroscopic, optical and magnetic properties. Crystals, 7(3), pp.92.

ARO Journal: Volume 5, No. 2 (2017)
Published
2017-07-18
How to Cite
Alsalihi, E. I., Al-Fahdawi, A. S. and Meena, B. I. (2017) “Synthesis and Characterization of Sodium Diphenylcarbamodithioate Ligand [L] and its Cobalt, Nickel, and Copper Complexes”, ARO-THE SCIENTIFIC JOURNAL OF KOYA UNIVERSITY, 5(2), pp. 1-5. doi: 10.14500/aro.10198.
Issue
Vol. 5 No. 2 (2017): Issue Nine
Section
Articles

Copyright (c) 2017 Eman I. Alsalihi, Aeed S. Al-Fahdawi, Bashdar I. Meena

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.

Authors who choose to publish their work with Aro agree to the following terms:

  • Authors retain the copyright to their work and grant the journal the right of first publication. The work is simultaneously licensed under a Creative Commons Attribution License [CC BY-NC-SA 4.0]. This license allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

  • Authors have the freedom to enter into separate agreements for the non-exclusive distribution of the journal's published version of the work. This includes options such as posting it to an institutional repository or publishing it in a book, as long as proper acknowledgement is given to its initial publication in this journal.

  • Authors are encouraged to share and post their work online, including in institutional repositories or on their personal websites, both prior to and during the submission process. This practice can lead to productive exchanges and increase the visibility and citation of the published work.

By agreeing to these terms, authors acknowledge the importance of open access and the benefits it brings to the scholarly community.

Crossref
Scopus
Google Scholar
Europe PMC